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Electron Electronics Data Sheet
Rosin free solder (170-161) supplied by Warton Metals.

Warton Omega Rosin Free Cored Solder Wire
Product Name:
Omega Rosin Free Cored Solder Wire
Manufactured By:
Warton Metals Limited
Grove Mill Commerce Street
Haslingden Lancashire
ENGLAND
Tel: +44 (0)1706 218888
Fax : +44 (0)1706 221188
Description
Omega Rosin Free Cored Solder Wire is a flux ‘core’
contained in Warton High Purity Cored Solder Wire. Omega contains no rosin
(colophony), resin acids, pine oil or other naturally occurring derivatives from
pine trees and has been specifically designed to reduce the number of world-wide
cases of industrial asthma, related to rosin usage within a cored solder wire.
Omega provides excellent wetting whilst leaving a minimal no clean, clear
residue. Cleaning by batch or in-line processes is not suitable, however, if
residues need to be removed use Warton Total Clean 200 aerosol cleaner.
Omega Flux Type & Specification
Omega is rosin free and formulated without the use of halides
and is supplied as a 3%, 2% and 1% flux content wire.
Omega is rated as an M-OR-L0 flux type in accordance with
J-STD-004 and passes Bellcore TR-NWT-000078 / J-STD-004 copper mirror
corrosion requirements.
Omega passes Bellcore TR-NWT-000078 / J-STD-004 surface
insulation resistance requirements.
Bellcore surface insulation resistance requirement
Hand Soldered test coupons, 35°
C/85%RH. 5day test. 4 days with bias voltage. Min req.2x10(4)Megohms.
Omega - 1x10(8)Megohms
JSTD-004 surface insulation resistance requirement
Wave soldered solution, 85°
C/85%RH.7Days with bias voltage min req. 100 Megohms.
Omega - 96 hours 1.1Gohms 168 hours 1.2 Gohms
High Purity Solder Alloy
In 1994 a single European standard, EN 29453 (ISO 9453),
superseded all other European national standards, BS 219, DIN 1707, NFC 90-550.
Other equivalent international standards include QQS 571E, ASTM B32 and
JIS-Z-3382.
|
Warton Part No: |
EN 29453 |
QQS 571E |
BS 219
*DIN 1707 |
|
63/37 |
1a |
Sn63Pb37 |
AP |
|
60/40 |
2a |
Sn60Pb40 |
KP |
|
50/50 |
3a |
Sn50Pb50 |
F |
|
45/55 |
4 |
- |
R |
|
40/60 |
5 |
Sn40Pb60 |
G |
|
35/65 |
6 |
Sn35Pb65 |
H |
|
30/70 |
7 |
Sn30Pb70 |
J |
|
20/80 |
- |
Sn20Pb80 |
V |
|
15/85 |
- |
- |
W |
|
99C |
23 |
- |
99C |
|
97C |
24 |
- |
- |
|
Alloy No 1 |
26 |
- |
*Sn50PbCu |
|
Alloy No 2 |
25 |
- |
*Sn60PbCu2 |
|
HMP 5S |
34 |
- |
5S |
|
LMP 62S |
30 |
Sn62Pb36Ag2 |
62S |
|
96S |
28 |
Sn96Ag04 |
96S |
|
95A |
18 |
Sn95Sb5 |
95A |
|
TLS/5 |
- |
- |
- |
|
TIN |
- |
- |
- |
|
TSC |
- |
- |
- |
The table above illustrates the equivalent Warton High
Purity Solder Alloy in relationship to EN 29453, QQS-571E, BS-219 and
DIN-1707.
Warton High Purity Solder Alloys are
manufactured using only the 'Highest Purity Virgin Materials' this being part of
Warton’s simple philosophy that the best raw materials lead to the best
finished products.
Typical batch analysis: High Purity Tin
|
Sn |
Sb |
Pb |
Cu |
Zn |
|
99.95 |
0.009 |
0.002 |
0.0002 |
0.0001 |
|
Fe |
As |
Ag |
Bi |
In |
|
0.002 |
0.002 |
0.0001 |
0.0001 |
0.0003 |
Typical batch analysis: High Purity Lead
|
Sn |
Sb |
Pb |
Cu |
Zn |
|
0.001 |
0.002 |
99.99 |
0.003 |
0.0001 |
|
Fe |
As |
Ag |
Bi |
In |
|
0.002 |
0.0005 |
0.002 |
0.005 |
0.0003 |
Typical batch analysis: Warton High Purity 63/37
|
Sn |
Sb |
Pb |
Cu |
Zn |
|
63.0 |
0.0095 |
rem |
0.0007 |
0.0002 |
|
Fe |
As |
Ag |
Bi |
In |
|
0.002 |
0.001 |
0.0005 |
0.0003 |
0.0003 |
These consistent high standards apply to all Warton High
Purity Solder Alloys.
Solder Alloys Containing Lead
|
Warton
Part No |
Sn %
Tin |
Pb %
Lead |
Cu %
Copper |
Ag %
Silver |
Sb %
Antimony |
|
63/37 |
62.5-63.5 |
Rem |
- |
- |
- |
|
60/40 |
59.5-60.5 |
Rem |
- |
- |
- |
|
50/50 |
49.5-50.5 |
Rem |
- |
- |
- |
|
45/55 |
44.5-45.5 |
Rem |
- |
- |
- |
|
40/60 |
39.5-40.5 |
Rem |
- |
- |
- |
|
35/65 |
34.5-35.5 |
Rem |
- |
- |
- |
|
30/70 |
29.5-30.5 |
Rem |
- |
- |
- |
|
20/80 |
19.0-20.0 |
Rem |
- |
- |
- |
|
15/85 |
14.0-15.0 |
Rem |
- |
- |
- |
|
Alloy No 1 |
49.5-50.5 |
Rem |
1.2-1.6 |
- |
- |
|
Alloy No 2 |
59.5-60.5 |
Rem |
1.6-2.0 |
- |
- |
|
HMP 5S |
4.8 - 5.2 |
Rem |
- |
1.2-1.8 |
- |
|
LMP 62S |
61.5-62.5 |
Rem |
- |
1.8-2.2 |
- |
|
TLS/5 |
4.8-5.2 |
Rem |
- |
0.8-1.2 |
- |
Lead Free Solder Alloys
In response to increasing environmental awareness and the
drive for new legislation (forcing greater end of product life responsibility),
Warton Metals offer a complete range of `lead free’ alloys to suit all
applications. See table below.
|
Warton
Part No |
Sn %
Tin |
Cu %
Copper |
Ag%
Silver |
Sb %
Antimony |
|
99C |
Rem |
.45 - .9 |
- |
- |
|
97C |
Rem |
2.5-3.5 |
- |
- |
|
96S |
Rem |
- |
3.5-4.0 |
- |
|
95A |
Rem |
- |
- |
4.5-5.5 |
|
TIN |
100 |
- |
- |
- |
|
TSC |
95.5-96 |
0.5-1 |
3.3-4 |
- |
The table above shows the elements included in each alloy.
Other important properties when selecting the correct alloy
are the working temperatures and the ultimate strength of the soldered joint.
The following table shows both working temperatures and
ultimate tensile strength of Warton material. The table indicates that a maximum
in tensile strength exists in the eutectic composition. The ultimate tensile
strengths listed below refer to the bulk solder. The values are only a guide to
the relative strength of identical joints made with the solder alloys at room
temperature. The table should not be used to calculate exact joint strengths,
which depend on a number of factors.
|
Warton
Part No |
Melting
range ºC |
Min junction
temp ºC |
N/mm² |
Tons/In² |
|
63/37 |
183 |
245 |
67 |
4.3 |
|
60/40 |
183-188 |
248 |
48 |
3.1 |
|
50/50 |
183-212 |
272 |
47 |
3.1 |
|
45/55 |
183-224 |
284 |
47 |
3.1 |
|
40/60 |
183-234 |
294 |
47 |
3.1 |
|
35/65 |
183-244 |
304 |
- |
- |
|
30/70 |
183-255 |
315 |
49 |
3.2 |
|
20/80 |
183-275 |
335 |
51 |
3.3 |
|
15/85 |
227-288 |
348 |
49 |
3.2 |
|
99C |
227 |
287 |
- |
- |
|
97C |
230-250 |
310 |
- |
- |
|
Alloy No. 1 |
183-215 |
275 |
55 |
3.5 |
|
Alloy No.2 |
183-190 |
250 |
- |
- |
|
HMP 5S |
296-301 |
361 |
36 |
2.3 |
|
LMP 62S |
179 |
239 |
92 |
5.9 |
|
96S |
221 |
281 |
54 |
3.5 |
|
95A |
236-243 |
303 |
31 |
2.0 |
|
TLS/5 |
296-301 |
361 |
- |
- |
|
TIN |
232 |
- |
- |
- |
|
TSC |
217 |
- |
- |
- |
Wire gauge ( Diameter )
The wire gauge ( diameter ) for Warton Omega is
represented as SWG. ( Standard wire gauge ) The equivalent imperial and metric
values are shown below.
|
Swg |
10 |
11 |
12 |
13 |
14 |
|
mm |
3.25 |
2.95 |
2.64 |
2.34 |
2.03 |
|
Inch |
0.128 |
0.116 |
0.104 |
0.092 |
0.080 |
|
Swg |
16 |
18 |
20 |
21 |
22 |
|
mm |
1.63 |
1.22 |
0.914 |
0.813 |
0.711 |
|
Inch |
0.064 |
0.04 |
0.036 |
0.032 |
0.028 |
|
Swg |
24 |
26 |
28 |
30 |
32 |
|
mm |
0.599 |
0.457 |
0.376 |
0.315 |
0.274 |
|
Inch |
0.022 |
0.018 |
0.014 |
0.012 |
0.010 |
Packaging
Warton Omega Rosin Free Cored Solder Wire is
supplied on 0.25Kg, 0.5Kg, 2.5Kg, 3Kg, 5Kg, 10Kg, 15Kg and 25Kg reels.
MATERIAL SAFETY DATASHEET
|
Section 1. Identification of the substance / preparation and of the
company / undertaking |
|
Product Name:
Manufactured By:
Emergency Telephone:
Emergency Fax: |
Omega Rosin Free Cored Solder Wire
Warton Metals Limited
Grove Mill, Commerce Street. Haslingden. Lancashire.
BB4 5JT. ENGLAND.
+44 (0)1706 218888
+44 (0)1706 221188 |
|
Warton’s product coding system precisely defines the features of a
particular type of solder wire.
For example: Omega Rosin Free Fast Flow 2% 63/37 22 swg No Clean Cored
Solder Wire. `Omega Rosin Free’ denotes the product name, Fast Flow 2%’
is the flux percentage , `63/37’ is the alloy (please see table below)
and ‘22swg’ is the standard wire gauge. |
|
Section 2. Composition / Information on Ingredients |
|
Flux cored solder wire is considered to be an article and is not
subject to the classification (Hazard Information and Packaging for
Supply) Regulations 1994, because it is not hazardous as supplied. However
this product may be hazardous In use and the information in this datasheet
- reflects the hazards associated with the solder reflow operations. |
|
Ingredient
Lead (dusts, heated vapours, fumes).
R33 - Danger of cumulative effects.
R61 - May cause harm to unborn child.
Tin
Activators and Inhibitors: |
Please use table below to determine the elements present in the alloy.
CAS No: Classification Symbol Risk phrases Safety
Phrases % Present
7439-92-1 T 33-61 See alloy table below
- - - - See alloy table below
<0.5 |
|
Warton Part No |
Tin (Sn) % |
Lead (Pb) % |
Copper (Cu) % |
Silver (Ag) % |
Antimony (Sb) % |
|
63/37 |
62.5-63.5 |
Rem |
- |
- |
- |
|
60/40 |
59.5-60.5 |
Rem |
- |
- |
- |
|
50/50 |
49.5-50.5 |
Rem |
- |
- |
- |
|
45/55 |
44.5-45.5 |
Rem |
- |
- |
- |
|
40/60 |
39.5-40.5 |
Rem |
- |
- |
- |
|
35/65 |
34.5-35.5 |
Rem |
- |
- |
- |
|
30/70 |
29.5-30.5 |
Rem |
- |
- |
- |
|
20/80 |
19.0-20.0 |
Rem |
- |
- |
- |
|
15/85 |
14.0-15.0 |
Rem |
- |
- |
- |
|
99C |
Rem |
- |
.45 - .9 |
- |
- |
|
97C |
Rem |
- |
2.5-3.5 |
- |
- |
|
Alloy No 1 |
49.5-50.5 |
Rem |
1.2-1.6 |
- |
- |
|
Alloy No 2 |
59.5-60.5 |
Rem |
1.6-2.0 |
- |
- |
|
HMP 5S |
4.8 - 5.2 |
Rem |
- |
1.2-1.8 |
- |
|
LMP 62S |
61.5-62.5 |
Rem |
- |
1.8-2.2 |
- |
|
96S |
Rem |
- |
- |
3.5-4.0 |
- |
|
TIN |
100 |
- |
- |
- |
- |
|
95A |
Rem |
- |
- |
- |
4.5-5.5 |
|
TLS/5 |
4.8-5.2 |
Rem |
- |
0.8-1.2 |
- |
|
TSC |
95.5-96 |
- |
0.5-1 |
3.3-4 |
- |
|
Section 3. Hazards Identification |
|
|
Main Hazards:
Health Effects: Inhalation:
Health Effects: Ingestion
Health Effects: Skin
Health Effects: Eyes |
Thermal burns from contact with molten product. Danger
of cumulative effects. See hazardous decomposition products.
Solder alloys containing lead give off negligible lead
fume at normal soldering temperatures and at temperatures up to 500ºC.
Lead is harmful if absorbed into the body and can cause birth defects and
other reproductive harm. Exposure to dust of processing fumes may have the
following effects:- gastrointestinal irritation. Vomiting, systematic
effects similar to those resulting from ingestion. Because of slow
elimination from the body repeated exposure may result in accumulation.
Contains lead which is a cumulative poison. Long term
effects may include: anaemia, fatigue, abdominal pain, anorexia,
constipation or diarrhoea, reduction in the oxygen carrying capacity of
the blood. Hot material will cause thermal burns.
Molten metal may cause severe damage to skin tissue.
Molten metal may cause severe damage and may result in
loss of vision. |
|
Section 4. First Aid Measures |
|
|
Inhalation:
Skin Contact:
Eye Contact:
Ingestion: |
In case of exposure to processing fumes: Remove from
exposure. Keep warm and at rest. Obtain medical attention urgently.
Wash hands with soap and water after handling solder
wire. If any skin irritation develops seek medical attention. In case of
contact with molten metal immediately flood affected area with cold water.
Obtain medical attention.
Flux fumes may irritate the eyes. The flux may spit
during soldering. Flush immediately with plenty of water. for at least 15
minutes, holding the eye open. In cases where spitting flux has entered
the eye seek medical attention.
Do not induce vomiting . Keep warm and at rest. Obtain
medical attention urgently. |
|
Section 5. Fire Fighting Measures |
|
|
Suitable extinguishing media:
Do not use:
Exposure hazards:
Protective measures: |
Not combustible. Select extinguishing agent appropriate
to other materials involved.
Water jet
High temperatures above 500ºC may produce heavy metal
dust, fumes and/or vapours. The medium will give rise to irritating fumes
in a fire.
Fire fighters should wear full protective clothing and
breathing apparatus operated in positive pressure mode. |
|
Section 6. Accidental Release Measures |
|
|
Personal precautions:
Environmental precautions:
Methods of clearing up: |
Refer to Section 8, Personal Protection. Wear
appropriate protective clothing.
Refer to Section 13, Disposal. Try to prevent the
material from entering drains or water courses.
Place in closed container for subsequent disposal or
recovery by Warton. Avoid creating a dust. |
|
Section 7. Handling & Storage |
|
|
Handling:
Storage: |
The fumes produced during use should be extracted away
from the breathing zone of the operators. Ensure that the general area is
well ventilated. Wash the hands with soap and warm water after handling
soldering products, particularly before eating and drinking or smoking.
Avoid contact with eyes, skin and clothing. Avoid breathing metal fumes
from heated material.
These products should be stored in a cool dry area.
Keep out of the reach of children and away from food and drink. |
|
Section 8. Exposure Controls & Personal Protection |
|
|
In normal soldering operations where the temperature is below 500ºC
the exposure to lead will be minimal and the risks from the toxic effects
of lead insignificant. (Ref: Approved Code Of Practise Supporting the
Control of Lead at Work Regulations). |
|
|
Occupational Exposure Limits:- Substance
Activators & Inhibitors, Tin, Lead: Control of Lead at Work
Regulations: 0.15mg/m³ 8h TWA |
|
|
Personal Protection:-
Respiratory protection:
Eye Protection:
Body Protection:
Hand protection:
Biological Standards:
References:
Engineering Control Measures: |
Not generally required unless there is inadequate
extraction during use. Dust respirator if conditions are dusty.
Respiratory protection if there is risk of breathing mists or vapours from
heated material.
Operators should wear safety glasses or goggles to
protect the eyes from spitting flux.
Normal work wear
Leather, thick textile or other thermal gloves. If
handling hot material.
Employees should be under medical surveillance if the
risk assessment made under the Control of lead at Work regulations
indicate they are likely to be exposed to significant concentration of
lead, or if an employment medical adviser or appointed doctor certifies
that an employee should be under medical surveillance.
A woman employed on work which exposes her to lead
should notify her employer as soon as possible if she becomes pregnant.
The employment medical advisor/appointed doctor should be informed of the
pregnancy. Under the Management of Health & Safety at Work (Amendment)
Regulations 1994, employers should assess the risks at work to the health
of pregnant workers and workers who have recently given birth or are
breast feeding.
EH40 Occupational Exposure Limits (published annually).
Fumes from the soldering process should not be
breathed. Ventilation should always be used. |
|
Section 9. Physical & Chemical Properties. |
|
Appearance / colour:
Odour:
Boiling point ºC:
Flash point ºC:
Explosive / oxidising:
Viscosity:
Vapour pressure:
Evaporation rate:
Flammability: |
Grey wire
-
N/A
N/A
N/A
N/D
N/A
N/A
N/A |
pH/Concentration:
Melting RangeºC:
Auto ignition temperature ºC:
Explosive limits (% vol):
Solubility/miscibility:
Volatile content (V.O.C):
Vapour density (air = 1):
Conductivity
Specific Gravity: |
N/D
See table below
N/A
N/A
Insoluble in water
N/D
N/A
N/D
N/A |
|
Warton Part No |
Melting range ºC |
Warton Part No |
Melting range ºC |
|
63/37 |
183 |
99C |
227 |
|
60/40 |
183-188 |
97C |
230-250 |
|
50/50 |
183-212 |
Alloy No. 1 |
183-215 |
|
45/55 |
183-224 |
Alloy No.2 |
183-190 |
|
40/60 |
183-234 |
HMP 5S |
296-301 |
|
96S |
221 |
LMP 62S |
179 |
|
TIN |
232 |
TLS/5 |
296-301 |
|
95A |
236-243 |
TSC |
217 |
|
Section 10. Stability & Reactivity |
|
|
Conditions to avoid:
Materials to avoid: |
If solder is exposed to temperature over 500ºC lead
dust, fume and /or vapours may be produced.
Solder will react with concentrated acid to release
poisonous fumes of nitric oxide. This will in turn oxidise to nitrogen
dioxide, a red gas with a pungent odour. If personnel are extensively
exposed to these gases then immediate medical attention should be sought,
as symptoms can be delayed for a considerable time period and can be
fatal.
Solder may react with other strong acids to release
highly flammable / explosive hydrogen gas. |
|
Section 11. Toxicological Information (
toxic effects arising from exposure based on experimental and non
experimental data) |
|
|
Inhalation:
Eye contact: Flux fume
Skin contact:
Ingestion:
Acute toxicity:
Chronic Toxicity:
Reproductive Toxicity: |
Main route of exposure for flux fumes. Providing
soldering temperature is below 500ºC the amount of lead in the fume
should be negligible.
The flux fumes may irritate the eyes.
Not normally regarded as an industrial hazard, but lead
can be transferred from the skin onto food, cigarettes etc., if a high
standard of personal hygiene is not exercised.
Not applicable
Lead can cause weakness, vomiting, loss of appetite,
convulsions and stupor.
Lead can cause weakness, insomnia, hypertension,
headaches and pains in the joints. Chronic exposure to lead may result in
damage to the blood - forming, nervous, urinary and reproductive systems.
Lead is classified as a 2B carcinogen by the IARC (1987). Evidence for
carcinogenity is adequate in animals but inadequate in humans.
The placenta offers no barrier to the transport of lead
from the mothers blood stream to that of the foetus. |
|
Section 12. Ecological Information |
|
|
(Possible environmental effects and behaviour /ODP/aquatic toxicity):
Bio-accumulation
Ecotoxicity:
Degradability: |
Lead is not degradable and will persist in the
environment. Lead is insoluble in water and is not attacked by most
inorganic acids and bases. For this reason lead in small quantities is
often disposed of in landfill sites, however this is not recommended. (See
section 13. Disposal Considerations).
Limited information indicates a potential to
bioaccumulate.
The product is rated as non hazardous to aquatic
species.
This product is expected to be resistant to
biodegration. |
|
Section 13. Disposal Considerations |
|
|
(Safe disposal of product, its residues and packaging materials): |
Waste solder wire should be put in metals tins
(supplied free of charge) and returned to Warton for disposal. Disposal
should be in accordance with the relevant local and national legislation.
In the UK this is the Control Of Pollution Act 1974, the Environmental
Protection Act 1990 and regulations made under them. See also Sections 7
& 8 for handling precautions and personal protection where applicable.
Wastes containing high levels of lead oxides are
classified as a ‘special waste’ under the COPA (Special Waste
Regulations 1996 and must be disposed of in accordance with those
regulations. |
|
Section 14. Transport Information |
|
| |
Solder Wire is not classified as hazardous for transportation. |
|
Section 15. Regulatory Information |
|
| |
Flux cored solder wire is considered to be an article and is not
subject to the classification (Hazard Information and Packaging for
Supply)Regulations 1994, because it is not hazardous as supplied. However
this product may be hazardous in use and the information in this datasheet
reflects the hazards associated with the solder reflow operations.
S37 Wear suitable gloves
Contains lead |
|
Section 16. Other Information |
|
|
Recommended uses and restrictions:
Publications references: |
Use only as directed.
Compiled in accordance with CHIP 2 Regulations 1994. HSE Approved Code
Of Practise, document L62. Dangerous Substances Directive 57/548/EEC as
amended by directive 92/32/EEC. Dangerous Preparations Directive 88/379/EE
as amended by Directive 90/492/EEC.Lead at Work Directive 82.605/EEC. The
Health & Safety at Work Act 1974. The Control Of Lead at Work
Regulations 1980. The Control of Substances Hazardous to Health
Regulations 1994. The Management of Health and Safety at Work Regulations
1992. The Management of Health and Safety at Work (Amendment) Regulations
1994. HS (G) 37: An Introduction to Local Exhaust Ventilation. HS (G) 53:
Respiratory Protective Equipment - A practical guide for users. HS (G) 65:
Successful Health & Safety Management’s. HS (G) 97: A Step by step
Guide to the Coshh Regulations. MS24: Health Surveillance of Occupational
Skin Disease. COSHH: Guidance for employers Approved Code of Practise -
Management of Health & Safety at Work. |
|
Section 17. Revision Dates |
|
|
Revised Date / Initials:
Replacing:
Legend: |
August 1999/ VHM
All previous health and safety datasheets
N/A = Not applicable or available at time of printing.
N/D = Not determined or not determinable.
Est. = Estimated |
|
The information and recommendations on this sheet
relate to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process.
The information is given in good faith and the best of Warton Metals Ltd
knowledge. The information is believed accurate and reliable at the time
of preparation. Nothing herein is to be construed as a guarantee, express
or implied - in all cases it is the responsibility of the user to
determine the applicability of this information or the suitability of the
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